Photochromic Dyes

Subcategories:
Ranbar Pigment

Spirooxazine Photochromic dye Ranbar DP7030

Spirooxazine Photochromic dye Ranbar DP7030

Name: Photochromic dyes
Brand: Ranbar Brown DP7030
Chemical structure: Spiroxazine
Temperature resistance: 220℃
Color change form: colorless to brown
Appearance and shape: white crystalline powder
Characteristics: high transparency, high sensitivity to light, bright color saturation, solvent resistance, easy to disperse
Uses: plastics, coatings, inks

Product Description:
Ranbar Brown DP7030 is a spirooxazine-structured colorless to brown photochromic dye that changes from transparent to brown by changing its chemical structure after absorbing ultraviolet light (usually from the sun or a UV lamp), and then changes back to transparent when the UV light source is removed. Depending on the application, they can cycle through color changes repeatedly, with the number of cycles determined primarily by the matrix in which the photochromic dye is embedded. They can also be changed from one color to another by combining them with permanent pigments.

Schematic diagram of the molecular changes of photochromic dyes

The principle of color change in spiro-oxazine photochromic dyes:
The spiro form of oxazine is a colorless dye, the conjugated system of oxazine and another aromatic part of the molecule are separated by a sp³ hybridized "spiro" carbon atom, upon UV irradiation, the bond between the spiro carbon and the oxazine is broken, the ring opens up, the spiro carbon achieves an sp² hybridization and becomes planar, followed by a rotation of the aromatic group, whose π-orbitals are aligned with the rest of the molecule. Finally, a conjugated system is formed with the ability to absorb visible light photons, resulting in colorful colors. When the UV source is removed, the molecule gradually relaxes to the ground state, the carbon-oxygen bond is re-formed, the spiro carbon becomes sp³ hybridized again, and the molecule returns to its colorless state.

These forms of photochromic dyes are thermodynamically unstable and revert to a stable form in the dark unless cooled to low temperatures, and their lifetimes are also affected by UV irradiation, and like most organic dyes they are susceptible to degradation by oxygen and free radicals, and incorporation of dyes into polymer matrices, addition of stabilizers, or provision of barriers to oxygen and chemicals can extend the photochromic dye service life.

Product Applications:
Ranbar photochromic dyes can be used in many novel applications to create new and innovative products and promotional items, such as company logos or brand names on fabrics or garments, engraving, stencil and screen printing, T-shirts, fashion, children's clothing, party dresses, toys, cosmetics, nail polishes, eyeglasses and sunglasses lenses, thermometers and temperature indicators, ultraviolet indicators, footwear, packaging, glassware, ceramics, plastics, anti-counterfeit printing, security and industrial applications and more.

Application Examples of Photochromic Dyes

Precautions:
●Photochromic dyes need to be dissolved in a suitable medium (e.g. resin) in order to produce the photochromic phenomenon. The polarity of the medium has a great influence on the color change performance of this product, so it is recommended to make a sample to confirm the state of color development before use.

●Avoid simultaneous use with UV absorbers. High sensitivity to polarity, different additives or use of different substrates may cause color difference.

●The decomposition temperature of photochromic dyestuff is low, if there is a high temperature process, it is recommended that the processing temperature should not be higher than 220 degrees Celsius, and the processing time should not be more than 30 minutes. Reducing the processing temperature or shortening the processing time at high temperature will help to improve the color change performance of the final product, and it is recommended that the customer conducts a small test before use.

●It is highly susceptible to environmental factors such as light, oxygen, pH value, etc. Long-term exposure to ultraviolet rays will result in light aging phenomenon, which will reduce the ability of photochromic dyestuffs to change color, which will be manifested by the shortening of the service life or even the loss of the ability of photochromic dyestuffs, so please pay attention to the sealing of containers, and store them in a dry place away from light.

model Color - colorless to colored hue solvent Temperature ℃ features Application field
DP1220 Fuchsia
Blue Red
Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP1380 Fuchsia Yellow Red Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP1610 Bright Red Yellow Red Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP2070 Orange Red Orange Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP2050 Orange Yellow Orange Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP3080 Yellow Red Yellow Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP4010 Green Green Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP4013 Green Dark Green Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP5060 Blue Royal Blue Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP6008 Purple Red Purple Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP6010 Violet Violet Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP6014 Violet Dark Violet Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP7030 Brown Red Brown Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink
DP0080 Grey Red light Black Toluene, EA, AC, MeOH, THF 220 High transparency Coatings, plastics, ink

Core Services
3 large Warehouses

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